Galvatron is the Decepticon leader from the Transformers series, the rebuilt form of Megatron. He crosses into Evangelion territory only by mention: in the crossover story Transformers Mode "EVA", Starscream briefly considers turning his stolen Angel power against him.
As a Decepticon, Galvatron is a transforming war machine of the Transformers mythos, distinguished by being Megatron remade into a new body. The Evangelion crossover never depicts him directly, so it adds nothing new to his look.
The crossover offers no window into his temperament beyond his standing: he commands the Decepticons, and Starscream nurses a grudge bitter enough that revenge against Galvatron is the first use the newly empowered traitor imagines for his stolen strength.
Galvatron never steps on stage in Transformers Mode "EVA". After Starscream seizes the body of an Angel and gains its power, he muses about settling scores with Galvatron, then decides that eliminating Optimus Prime comes first. Millions of years old, the Decepticon leader remains offstage for the entire story.

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Yes, Galvatron is the rebuilt form of Megatron, the Decepticon leader remade into a new body.
Galvatron only enters Evangelion territory by mention in the crossover story Transformers Mode "EVA", where Starscream briefly considers using his stolen Angel power for revenge against him.
No, Galvatron never appears on stage in Transformers Mode "EVA". He remains offstage for the entire story, referenced only in passing.
In Transformers Mode "EVA", Galvatron's rivals include Starscream, who nurses a grudge against him, and Optimus Prime, his longtime Decepticon adversary.
The story describes Galvatron as millions of years old, reflecting his long history as the Decepticon leader.
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