
Reiju, nicknamed Poison Pink, is the eldest of the five Vinsmoke children and the family's only daughter. She ranks as a Germa Kingdom princess and leads troops in its army Germa 66, quietly siding with the Straw Hats over the course of the Whole Cake Island events.
The spiral-shaped curly eyebrows that brand every Vinsmoke, resembling a six, identify Reiju as well, though hers coil in mirrored opposite directions rather than running parallel like her brothers'. Her build is slim, and her shoulder-length hair carries a pale pink tone, falling across the right eye and curling up at the tips. Purple eyes and a soft pink lip color finish her face in the manga, with the anime nudging both toward deeper pink and blue. A number six is tattooed on each of her thighs, marking her allegiance to the organization.
Her fighting outfit is a revealing pale pink raid suit, split open at the front and trimmed with gold target rings that play on the zero in her name. She rounds it out with gauntlets in dark pink, a blue ascot, numbered headphones, and a cloak shaped after the wings of a moth. Out of combat she has appeared in silky white dresses, ceremonial royal capes, and infirmary clothing after taking a wound. As a child her hair was shorter, and she once towered over her siblings before each of them grew past her in adulthood.
Under a cold, careful surface molded by her family's militarism and her father's scorn for compassion, Reiju conceals real tenderness. She doles out her kindness sparingly, sharing it only when doing so risks neither her safety nor her ease. In childhood she laughed along while her brothers brutalized Sanji, yet she privately admitted the laughter was a shield, and she nursed him with care whenever the others were away. Even now Sanji counts her and their mother as the sole kin who ever treated him gently.
Guarded and seldom open, she cloaks her embarrassment over her lineage behind a show of pride in Germa's bygone glories. Privately she sees the kingdom as a war engine that the planet would be healthier lacking, a verdict she applies to her father, three of her brothers, and herself alike. Keen instinct and a calculating mind shape her too: she alone questioned Pudding's sweetness, and she exploited Sanji's soft spot for beautiful women to advance the marriage. Her manner can edge toward flirtation, as when she pressed her lips to Luffy's to pull out venom before the two had ever been introduced.
Genetic engineering left Reiju with superhuman strength, speed, and toughness, backed by an exoskeleton and a swift healing rate. She bent steel bars as a young girl, snatched a rampaging Luffy off his feet one-handed, and booted her brother Yonji clean off a ship into the water. Her grasp of medicine runs deep, spanning battlefield injuries and toxicology, allowing her to gauge poison symptoms exactly. As a Vinsmoke she also commands political power over the kingdom and the run of her family's riches and technology.
Her hallmark is poison mastery, the root of the Poison Pink title. She can draw lethal toxins out of a person through mouth-to-mouth contact and swallow them without harm, even relishing doses potent enough to fell a giant, as she did rescuing Luffy from stonefish venom. She likewise secretes poison and works it into her attacks, giving trouble even to Sweet Commander Smoothie. Her signature technique, Pink Hornet, expels toxic vapor that pierces and poisons her targets. Her raid suit guards against fire, bullets, and heavy strikes while supplying jet-driven flight.

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Yes, Vinsmoke Reiju is Sanji's older sister, the eldest of the five Vinsmoke children and the family's only daughter.
The wiki content does not depict Reiju as being in love with Luffy. Her only notable contact with him was extracting stonefish venom through a kiss before the two had ever been formally introduced, though her manner is often described as flirtatious.
Vinsmoke Reiju has a cold, careful exterior shaped by her family's militarism, but she conceals real tenderness, secretly cared for Sanji as a child, and ultimately sides with him and the Straw Hats, making her more good than evil at heart.
No, Vinsmoke Reiju's poison abilities and superhuman strength, speed, and toughness come from genetic engineering rather than a Devil Fruit.
Vinsmoke Reiju is known as Poison Pink for her mastery of poison, which lets her draw toxins out of a person through mouth-to-mouth contact, swallow them without harm, and secrete poison into attacks like her signature technique Pink Hornet.
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